Code:
<ul>
<li><a href="mylink">my link</a></li>
<li><a href="mylink">my other link</a></li>
</ul>
With the CSS
Code:
ul li a:hover {
background: #00386e;
color: #fff;
padding: 5px; /*just for a little breathing room*/
}
The same principles can be applied directly to an anchor if you wish. Just use the right selectors to get to it.
Good luck!